Structural characterization of a tetrametallic diamine-bis(phenolate) complex of lithium and synthesis of a related bismuth complex

Marcus W. Drover,Jennifer N. Murphy, Jenna C. Flogeras,Céline M. Schneider,Louise N. Dawe,Francesca M. Kerton

Polyhedron（2015）

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摘要

A tetra-lithium amine-bis(phenolate) ‘daisy-chain’ complex is shown to reversibly dissociate to give a centrosymmetric di-lithium species in solution. It can be used as a precursor for an amine-phenolate complex of bismuth.

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关键词

Lithium,N, O ligands,Coordination compounds,NMR studies,Bismuth

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