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Pressure-induced variations of MLCT and ligand-centered luminescence spectra in square-planar platinum(II) complexes

Alexandre Rodrigue-Witchel,David L. Rochester,Shu-Bin Zhao,Kevin B. Lavelle,J.A. Gareth Williams,Suning Wang,William B. Connick,Christian Reber

Polyhedron（2016）

Cited 16|Views6
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Abstract
MLCT luminescence transitions of square-planar platinum(II) complexes show small shifts to lower energy with increasing pressure. Ligand-centered (LC) transitions in similar compounds do not show significant shifts, providing an experimental criterion to distinguish different types of luminescence transitions.
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Key words
Luminescence spectroscopy,Variable-temperature spectroscopy,Variable-pressure spectroscopy,Cyclometallated platinum(II) complexes,NCN-coordinating ligand
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