Copper(I) complexes bases on a new indazol-4,7-dione ligand
Polyhedron(2013)
摘要
The synthesis of two new isomeric ligands, 1-(1-((2,6-diisopropylphenyl)imino)ethyl)-1H-benzo[f]indazole-4,9-dione (La) and 2-(1-((2,6-diisopropylphenyl)imino)ethyl)-2H-benzo[f]indazole-4,9-dione (Lb), and of their [Cu(I)(Lb)2] (ClO4) (1) homoleptic and [Cu(I)(Lb(PPh3)2] (ClO4) (2) heteroleptic copper(I) complex derivatives is reported. The chemical stability, and the spectroscopic and electrochemical properties of the complexes are discussed.
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关键词
Indazol-4,7 dione,Copper(I) complex,Homoleptic copper(I),Heteroleptic copper(I)
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