Syntheses, crystal structures and magnetic properties of two cyanide-bridged molecular squares MII2–CoII2 (M = Ru, Os) based on the diamagnetic cyanidometal M(dppm)2(CN)2

Yong Wang,Xiao Ma,Shengmin Hu, Yanlong Wang,Chunhong Tan,Yuehong Wen,Xudong Zhang,Tianlu Sheng,Xintao Wu

Polyhedron（2014）

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摘要

Two tetra-nuclear cyanide-bridged molecular square complexes [MII(dppm)2(CN)2(CoIICl2)]2 (M=Ru, 1; M=Os, 2) (dppm=bis(diphenylphosphino) methane) were synthesized and fully characterized. Temperature dependence of magnetic susceptibilities indicate the presence of a weak spin-canted anti-ferromagnetic in 1 and of only a weak anti-ferromagnetic coupling in 2.

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关键词

Diamagnetic cyanidometal bridge,Spin-canted,Os(II),Ru(II),Cobalt(II)

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