Electronic structure of hydrogenated carbon nanotubes studied by core level spectroscopy

M M Brzhezinskaya,V A Shmatko,G Yalovega, Anatoli Krestinin,I O Bashkin,Elena Bogoslavskaja

Journal of Electron Spectroscopy and Related Phenomena（2014）

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摘要

•The combined investigation of the H-SWNTs by highly chemically sensitive X-ray methods is presented.•The formation of the CH covalent bonds in the H-SWNTs is observed.•The SWNT graphite skeleton does not destroy during H atoms’ attachment.•The hybridization of the 2s and 2p valence electron states of the SWNT carbon atoms changes from the sp2 to sp3.

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关键词

Hydrogenated carbon nanotubes,Near edge X-ray absorption fine structure spectroscopy,X-ray photoelectron spectroscopy,Density functional calculations,Finite difference method

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