Enhancing the Ductility of Sn-Ag-Cu Lead-Free Solder Joints by Addition of Compliant Intermetallics
Journal of Electronic Materials(2013)
摘要
Tin (Sn)-rich lead (Pb)-free solders containing rare-earth (RE) elements have been shown to exhibit desirable attributes of microstructural refinement and enhanced ductility relative to conventional Sn-3.9Ag-0.7Cu lead-free solder, due to the unique mechanical properties of RE-Sn intermetallics. However, the roles of soft intermetallic phase in the enhanced ductility of Pb-free solder still need to be further investigated. In this paper, Ca and Mn were selected as doping elements for Sn-Ag-Cu solder. The mechanical properties of Ca-Sn and Mn-Sn intermetallics as a function of indentation depth were measured by nanoindentation using the continuous stiffness method (CSM). The microstructure and mechanical properties of as-reflowed Ca- and Mn-containing Sn-Ag-Cu solder joints were studied and compared with those of conventional Sn-Ag-Cu and RE-containing solder joints. It is shown that soft intermetallics result in higher ductility in Pb-free solders.
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关键词
Lead-free solder, intermetallic, Young’s modulus, hardness, nanoindentation, calcium, manganese
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