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Construction of Benzimidazoles and Benzoxazoles through the Molybdenum-Mediated Carbonylation of Aryl Halides

European Journal of Organic Chemistry(2015)

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摘要
The facile and efficient one-pot construction of benzimidazoles and benzoxazoles through the Mo(CO)6-mediated carbonylation of aryl halides was examined. In the process, Mo(CO)6 acted as a convenient and safe solid source of carbon monoxide. A wide range of substrates were tolerated to provide the corresponding products in fair to good yields without the need of gaseous CO or palladium catalysts.
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关键词
Synthetic methods,Carbon­ylation,Molybdenum,Carbonyl ligands,Fused-ring systems,Nitrogen heterocycles
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