Progress in the Synthesis of 2-Substituted Benzoxazoles Derivatives
CHINESE JOURNAL OF ORGANIC CHEMISTRY(2014)
Abstract
2-Substituted benzoxazole derivatives play important roles in pharmaceuticals, pesticide and coordination catalysis, so the synthetic methods for 2-substituted benzoxazoles have been attracted widely. Recently, a series of efficient green methods such as microwave irradiation, water as solvent, solvent-free, combinatorial chemistry and transition metal catalysis etc. have been used to synthesize 2-substituted benzoxazoles derivatives. Based on different starting materials and different methods, the recent advances in synthesis of 2-substituted benzoxazole are reviewed.
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Key words
2-substituted benzoxazoles,o-aminophenol,coupled reaction,transition metal catalysis,green chemistry
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