Copper-Catalyzed Direct Benzylation Of Beta-Ketoesters With N-Tosylhydrazones
CHINESE JOURNAL OF ORGANIC CHEMISTRY（2015）
Abstract
A simple and efficient method for the benzylation of beta-ketoesters by employing copper salt as a catalyst was developed. The mild reaction system and a wide range of substrates with high yields make the protocol very practical. It provides a new route for the synthesis of alpha-benzyl-beta-ketoesters.
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Key words
CuI, N-tosylhydrazones, beta-ketoesters, benzylation
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