V@CN催化的芳烃的氧气羟基化反应
Chinese Journal of Catalysis（2015）
Abstract
制备了V@CN催化剂,并用于氧气条件下芳烃的直接羟基化反应。结果表明,在V@CN催化剂作用下,带有不同吸电子基团(CN, NO2, COOH, CF3和COCH3)的芳烃均可被O2氧化得到相应的酚,产率中等。含有卤素(F, Cl和Br)的芳烃也可在该催化体系作用下转化为相应的酚。
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Key words
Hydroxylation,Vanadium,Arene,Oxygen,Graphitic carbon nitride
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