Nachweis der Zwischenstufen bei der sequenziellen Elektronen‐ und Wasserstoffabgabe aus einem Dicarbonylcobalthydrid‐Komplex

Angewandte Chemie(2013)

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Abstract
Schritt für Schritt: Für die H2-entwickelnde Oxidation eines Dicarbonylcobalthydrid-Komplexes mit dem sterisch abschirmenden 1,1′-Bis(diisopropylphosphanyl)ferrocen-Liganden lassen sich Elektronen- und Wasserstoff-Übertragungsschritte IR-spektroelektrochemisch und strukturell dokumentieren. Die Reaktionssequenz komplementiert den für Wasser-reduzierende Cobaltverbindungen mit weniger stark π-akzeptierenden Liganden diskutierten Mechanismus. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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cobalt
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