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Synthesis and characterization of fluorinated diblock copolymer of 2,2,2-trifluoroethyl methacrylate and methyl methacrylate based on RAFT polymerzation

Guanghan Li,Anhou Xu,Bing Geng, Shuaishuai Yang,Guangxing Wu,Shuxiang Zhang

Journal of Fluorine Chemistry（2014）

Cited 17|Views3
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Abstract
A fluorinated diblock copolymer of methyl methacrylate (MMA) and 2,2,2-trifluoroethyl methacrylate (TFEMA) was prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization. Its structure was well characterized and exhibited excellent performance than PMMA and random copolymer of MMA and TFEMA.
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Key words
Fluorinated acrylate,Diblock copolymer,Reversible addition–fragmentation chain transfer (RAFT),2,2,2-Trifluoroethyl methacrylate (TFEMA),Controlled copolymer
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