Coupling Reactions Of N-Propargyl Semi-Salen Compounds Induced By Ruthenium Complex

Organometallics(2014)

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摘要
The coupling reaction of N-propargyl semi-salen compound id on [Ru]-Cl ([Ru] = Cp(PPh3)(2)Ru) generates the carbene complex 3d containing a substituted 2H-chromene unit in 7 d. The precursor vinylidene complex 2d is isolated from the reaction of the propargyl group of 1d with [Ru]-Cl in 12 h. Addition of an o-cresol moiety to C alpha and C beta of the vinylidene ligand of 2d takes place in a longer reaction time to yield 3d. Reactions of [Ru]-Cl with other analogous compounds 1a, 1b, and 1c, in excess, also afford carbene complexes 3a, 3b, and 3c, respectively, in 48 h via a similar coupling process. Their precursor vinylidene complexes 2a, 2b, and 2c are also observed in 12 h. Structures of 2 and 3 are determined on the basis of spectroscopic data. The solid state structure of the dppe analogue 3a' is further confirmed by X-ray diffraction analysis. The added o-cresol part comes from compounds 1, instead of aldehyde which is confirmed by the cross-coupling reactions of 2 and 1 using mass spectrometry. For comparison, treatment of [Ru]Cl with the amine analogue 13b retaining the propargyl and phenol moieties yields no coupling product.
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关键词
Carbene Complexes,Ruthenium Catalysts
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