Diaquabis(1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
Acta Crystallographica Section E Structure Reports Online(2013)
Abstract
In the title compound, [Mn(C4H3N2O2)2(H2O)2], the Mn(II) ion is located on a twofold rotation axis and displays a distorted octa-hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands in the equatorial plane and two water mol-ecules in axial positions. In the crystal, O-H⋯O and N-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. π-π stacking inter-actions between the imidazole rings [centroid-centroid distances = 3.5188 (15) and 3.6687 (15) Å] further stabilize the structure.
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Key words
diaquabis1<i>h</i>-imidazole-4-carboxylato-κ<sup>2</sup><i>n</i><sup>3</sup><i>o</i><sup>4</sup>manganeseii
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