Ruthenium-catalyzed nucleophilic fluorination of halobenzenes

Andrey I Konovalov,Evgeniya O Gorbacheva,Fedor M Miloserdov,Vladimir V Grushin

CHEMICAL COMMUNICATIONS（2015）

引用 31|浏览15

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摘要

The first pi-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal fluorides (CsF, KF) in the presence of a Cp*Ru catalyst at 120-180 degrees C to give fluorobenzene.

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关键词

nucleophilic fluorination,ruthenium-catalyzed

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