Asymmetric catalysis of intramolecular N–H insertion reactions of α-diazocarbonyls
CHEMICAL COMMUNICATIONS(1996)
Abstract
Intramolecular N–H insertion reactions of α-diazocarbonyl substrates are catalysed by rhodium(II) carboxylates with catalyst-dependent competition with C–H insertion and β-elimination; asymmetric N–H insertion leading to a pipecolic acid derivative with ee up to 45% is achieved using chiral catalysts.
MoreTranslated text
Key words
asymmetric catalysis
AI Read Science
Must-Reading Tree
Example
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined