On the kinetics of the isomerization of glucose to fructose using Sn-Beta
Chemical Engineering Science(2014)
Abstract
Process design and techno-economic evaluation of glucose isomerization on Sn-Beta require reliable catalytic reaction rate expressions and kinetic constants. Here, the isomerization of sugars (glucose, fructose and mannose) in water using Sn-Beta is investigated at various temperatures ranging from 70 to 130°C. It is shown that the catalyst deactivates during the course of the reaction. A phenomenological model that describes the isomerization reaction in the presence of deactivation is developed and the corresponding kinetic constants are estimated from experimental data.
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Key words
Biomass,Sn-Beta,Isomerization,Glucose,Fructose,Kinetics
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