Deuterated dimethyl sulfoxide as a good NMR solvent for the characterization of alkali metal cyclopentadienides, amides, alkoxides and phenoxides
Journal of Organometallic Chemistry(2011)
摘要
A series of alkali metal cyclopentadienides, amides, alkoxides and phenoxides was characterized using NMR spectroscopy in deuterated dimethyl sulfoxide. Deuterated dimethyl sulfoxide showed very good stability and solubility for these compounds. Very nice and well resolved spectra were obtained for most compounds tested. The low cost of the solvent makes it possible to use it for the routine characterization of these alkali salts as the ligands in organometallic synthesis.
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关键词
Deuterated dimethyl sulfoxide,NMR solvent,NMR spectroscopy,Cyclopentadienides,Amides,Alkoxides
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