An improved method for the regioselective synthesis of highly substituted quinolines from Morita–Baylis–Hillman adducts
Cheminform(2015)
摘要
The synthesis of highly substituted quinolines was accomplished through a Heck reaction of substituted iodoanilines with Morita–Baylis–Hillman (MBH) adducts employing Nájera N-oxime derived palladacycle as catalyst. The reaction is completely regioselective and gives the products with good to excellent yields (up to 89%) with low catalyst loading and TONs of up to 89.
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关键词
Quinolines,Morita–Baylis–Hillman,Palladacycle,Regioselective
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