ChemInform Abstract: Amino Acids and Peptides. Part 87. Enantioselective and Diastereoselective Formation of syn‐3‐Hydroxy‐4‐amino Acids (syn‐ Statines) via Tetramic Acids.

Ulrich Schmidt,B Riedl,G Haas,Helmut Griesser, A H Vetter,Steffen Weinbrenner

Cheminform（1993）

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Abstract

Enantiomerically pure pyrrolidine-2,4-diones (tetramic acids) which can be diastereoselectively hydrogenated to syn-statines (4-amino-3-hydroxy-6-methylheptanoic acids) have been prepared by catalytic hydrogenation of 4-(benzyloxycarbonylamino)-3-oxocarboxylic acid esters.

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Key words

tetramic acids,diastereoselective formation

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