ChemInform Abstract: A Practical Synthetic Approach to Chiral (α‐Chloroalkyl)boronic Esters via Iridium‐Catalyzed Chemoselective Hydrogenation of Chloro‐Substituted Alkenyl Boronates.
ChemInform(2014)
摘要
AbstractThe use of a chiral iridium P,N‐complex as catalyst allows the synthesis of (α‐chloroalkyl)boronic esters with up to 94% ee accompanied by small amounts of dechlorination products.
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