ChemInform Abstract: A Practical Synthetic Approach to Chiral (α‐Chloroalkyl)boronic Esters via Iridium‐Catalyzed Chemoselective Hydrogenation of Chloro‐Substituted Alkenyl Boronates.

Stephen J. Roseblade,Eva Casas‐Arce,Ulrike Nettekoven,Ivana Gazic Smilovic,Antonio Zanotti‐Gerosa,Zdenko Casar

ChemInform（2014）

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摘要

AbstractThe use of a chiral iridium P,N‐complex as catalyst allows the synthesis of (α‐chloroalkyl)boronic esters with up to 94% ee accompanied by small amounts of dechlorination products.

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