ChemInform Abstract: Enantioselective Trapping of an α‐Chiral Carbanion of Acyclic Nitrile by a Carbon Electrophile.
Cheminform(2012)
摘要
α-Chiral nitrile carbanions generated by deprotonation of enantioenriched O-carbamoyl cyanohydrins (I) are trapped in situ with ethyl cyanoformate (II) to give corresponding ester derivatives (III) in high yields and good enantioselectivity.
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关键词
enantioselective trapping,acyclic nitrile,carbon electrophile,cheminform abstract
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