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ChemInform Abstract: Synthesis of 3,4‐Dimethylidene Oxacycles Through Prins‐Type Cyclization of Allenylmethylsilanes.

Cheminform(2011)

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摘要
Dimethylidene‐substituted oxolanes and oxepanes are synthesized by reaction of the corresponding silyl(allenyl)alcohols with aldehydes promoted by TmsOTf.
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关键词
allenylmethylsilanes,cheminform,synthesis,prins-type
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