ChemInform Abstract: One-Step Synthesis of Indanones Through NbCl5-Induced Friedel-Crafts Reaction.

Jader da Silva Barbosa,Gil Valdo Jose da Silva,Mauricio Gomes Constantino

Cheminform（2015）

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摘要

This Letter describes the use of NbCl5 as the Lewis acid in Friedel–Crafts reactions, in which a bifunctional electrophile reacts inter- and intramolecularly with an aromatic ring to produce a number of indanones in a single step, maintaining mild conditions and good yields.

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关键词

Synthesis of 1-indanone,Friedel–Crafts,Cycliacylalkylation,Niobium pentachloride,Lewis acid

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