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ChemInform Abstract: Synthesis of an Alkylidene 2‐Oxazolidinone via Gold‐Catalyzed Cyclization of a N‐Boc‐Allenylaniline.

Flavia C De Sousa Fonseca,Flavia M Araujo,Tanus Jorge Nagem,Tania T De Oliveira,Carlos Roque Duarte Correia,Jason G Taylor

Cheminform（2013）

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Abstract
Abstract N-Boc-allenylaniline undergoes cyclization in the presence of a catalytic amount of a cationic gold complex to exclusively form 2-oxazolidinones, whereas the N-Moc-allenylaniline affords dihydroquinolines. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.
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Allenes,catalyst,dihydroquinolines,gold,hydroarylation,2-oxazolidinones
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