ChemInform Abstract: Copper‐Catalyzed Aerobic Oxidations of 3‐N‐Hydroxyaminoprop‐1‐ynes to Form 3‐Substituted 3‐Amino‐2‐en‐1‐ones: Oxidative Mannich Reactions with a Skeletal Rearrangement.
Cheminform（2015）
摘要
The starting alkynes are treated with H2O, thiols and alcohols to produce β-oxamides or (E)-configurated 3-amino-2-en-1-ones.
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关键词
oxidative mannich reactions,aerobic oxidations,cheminform abstract,skeletal rearrangement,copper-catalyzed,n-hydroxyaminoprop
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