ChemInform Abstract: Diastereo‐ and Enantioselective Intramolecular 1,6‐C—H Insertion Reactions of α‐Diazo Esters Catalyzed by Chiral Dirhodium(II) Carboxylates.

Motoki Ito,Yuji Kondo,Hisanori Nambu,Masahiro Anada,Koji Takeda,Shunichi Hashimoto

Cheminform（2015）

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摘要

The first catalytic asymmetric 1,6‐C—H insertion reaction of α‐diazo esters catalyzed by 1 mol % of a chiral Rh‐complex is developed which provides facile access to optically active oxygen‐containing six‐membered cyclic core structures of biologically active natural products and pharmaceutical agents.

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关键词

carboxylates,cheminform abstract,reactions

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