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ChemInform Abstract: Oxidative Photoredox‐Catalytic Activation of Aliphatic Nucleophiles for C(sp3)—C(sp2) Cross‐Coupling Reactions

Emanuela Jahn,Ullrich Jahn

Cheminform（2015）

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Abstract
In the light you will find the road (Led Zeppelin): Visible-light photoredox catalysis leads the way in overcoming the reactivity limitations of alkyl nucleophiles in cross-coupling reactions. Iridium-triggered oxidative photoredox activation of alkyltrifluoroborate or carboxylic acids affords alkyl radicals, which undergo nickel-catalyzed cross-coupling reactions.
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aliphatic nucleophiles,reactions,cheminform abstract,photoredox-catalytic,cross-coupling
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