Spectroscopic and electrochemical studies of high-valent water soluble manganese porphyrine. Electrocatalytic water oxidation

Maria Alejandra Luna,Fernando Moyano,Leonides Sereno,Fabiana D Eramo

Electrochimica Acta（2014）

引用 18|浏览4

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摘要

•Chemical and electrochemical oxidation of [PMn(III)]Cl5 was studied.•[PMn(III)]Cl5 are characterized by Uv-vis spectroscopy and cyclic voltammetry.•Intermediates with higher oxidation states, [PMn(IV)=O]+4 and [PMn(V)=O]+5, are formed.•High oxidation current is due mainly to the water catalytic oxidation by [PMn(V)=O]+5.

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关键词

Manganese porphyrin,Electrocatalysis,Electrochemistry,Water oxidation

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