Structural and catalytic properties of mono- and bimetallic nickel–copper nanoparticles derived from MgNi(Cu)Al-LDHs under reductive conditions

Brindusa Dragoi,Adrian Ungureanu,Alexandru Chirieac,Carmen Ciotonea,Constantin Rudolf,Sebastien Royer,Emil Dumitriu

Applied Catalysis A: General（2015）

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摘要

•Highly dispersed (bi)metallic NiCu NPs derived from as-synthesized MgNi(Cu)Al-LDHs.•Extensive characterization of (bi)metallic NPs by in situ XRD, TEM, N2O titration.•(Bi)metallic NiCu NPs outstandingly active in hydrogenation of cinnamaldehyde.•Cu–MgAl-LDH is extremely active even after mild reduction at 150°C.

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关键词

Layered double hydroxides,Copper,Nickel,Nanoparticles,Hydrogenation,Cinnamaldehyde

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