Propane ammoxidation catalyst prepared by thermally induced spreading of Sb 2 O 3 on V/Al/O-mixed oxide

J Bilde,P Delichere,L Burel,Stephane Loridant,J M M Millet

Applied Catalysis A: General（2013）

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摘要

•Mixtures of Sb2O3 and V/Al/O mixed oxide are efficient in propane ammoxidation.•Sb2O3 and V/Al/O react forming a V1−xAlxSbO4 phase with Sb spreading over V/Al/O.•Sb2O3 addition is a mean to decrease total oxidation and increase propene formation.

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关键词

Propane ammoxidation,Vanadium–aluminum oxynitride,Antimony oxide,Synergetic effects,Mechanical mixtures

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