Graphitic carbon nitride nanosheet-assisted preparation of N-enriched mesoporous carbon nanofibers with improved capacitive performance

N-enriched mesoporous carbon nanofibers (NMCNFs) were prepared by an electrospinning technique using graphitic carbon nitride (g-C3N4) nanosheets both as sacrificial template and N-doping source. The resultant NMCNF film has a high N-doping level of 8.6wt% and a high specific surface area of 554m2g−1. When directly used as the electrode material for supercapacitor, the free-standing NMPCNF film shows a significantly improved capacitive performance including a higher specific capacitance (220Fg−1 at 0.2Ag−1) and a better rate capability (∼70% retention at 20Ag−1) than those of microporous carbon nanofiber film prepared using the same process without using g-C3N4 nanosheets (145Fg−1 at 0.2Ag−1 and ∼45% retention at 20Ag−1). Moreover, the NMCNFs show superior stability with only a ∼3% decrease of its initial capacitance after 1000 cycles at a high current density of 10Ag−1. More significantly, the energy density of a symmetrical supercapacitor (SC) based on the NMPCNF film can reach 12.5Whkg−1 at a power density of 72Wkg−1.