Acidic rearrangement of benzyl group in flavone benzyl ethers and its regioselectivity

Chongqing Wang,Xin Chen,Junhang Jiang,Hui Tang,Kongkai Zhu,Youjun Zhou,Canhui Zheng,Ju Zhu

Chinese Chemical Letters（2015）

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摘要

Complicated regioselectivity was observed in the acidic rearrangement of benzyl groups in flavone benzyl ethers. It probably determined by the steric hindrance, as well as the ease of electrophilic substitution reaction for benzyl cations.

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关键词

Benzyl-substituted flavone,Acidic rearrangement of benzyl group,Regioselectivity,Quantum chemical calculation

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