Morita-Baylis-Hillman Route to Dimethyl 2,3-Dihydrobenzo[b]oxepine-2,4-dicarboxylates and Methyl 2-(2-Carbomethoxybenzo[b]furan-3-yl)propanoates from Salicylaldehydes

Sanghyun Ahn,Seungsoon Jang,Youngkeun Kim,Keejung Lee

BULLETIN OF THE KOREAN CHEMICAL SOCIETY（2012）

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摘要

A new synthetic method for dimethyl 2,3-dihydrobenzo[b]oxepine-2,4-dicarboxylates and methyl 2-(2carbomethoxybenzo[b]furan-3-yl)propanoates by an intramolecular conjugate displacement reaction or an S(N)2 reaction of acetates of Morita-Baylis-Hillman adducts of methyl (2-formylphenoxy)acetates has been described.

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关键词

Morita-Baylis-Hillman,S(N)2-S(N)2 ' Reaction,2,3-Dihydrobenzo[b]oxepines,Benzo[b] furans,Methyl (2-formylphenoxy)acetates

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