Pt-catalysed intermolecular hydroamination of non-activated olefins using a novel family of catalysts: Arbuzov-type phosphorus metal complexes

Mireia Rodriguezzubiri,Stephane Anguille,Jeanjacques Brunet,Jeanclaude Daran

Journal of Molecular Catalysis A: Chemical（2013）

引用 17|浏览12

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摘要

Novel family of ligands for hydroamination. Arbuzov-type phosphorus-metal complexes in situ generated from alkylphosphites and Br−, PtBr2 (0.3mol%)/2P(OR)3/10nBu4PBr, allows good catalytic activities for the intermolecular hydroamination of ethylene and higher α-olefins (96% Markovnikov regioselectivity).

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关键词

Platinum,Phosphorus ligands,Arbuzov,Hydroamination,Halides

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