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Supramolecular Elastomers: Self-Assembling Star Blocks Of Soft Polyisobutylene And Hard Oligo(Beta-Alanine) Segments

Macromolecules(2015)

Cited 21|Views4
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Abstract
A series of novel self-assembling star-blocks consisting of M-w = 29 000 g/mol 3-arm polyisobutylene (PIB) stars and oligo(beta-alanine) end segments were synthesized and characterized. Starblocks containing beta-alanine dimers are viscous liquids, while those with tri-, tetra-, and penta(beta-alanine)s are elastic solids. According to IR spectroscopy, the beta-alanine dimer is partially hydrogen-bonded, while the trimer, tetramer, and pentamer are fully hydrogen-bonded and form beta-sheets. DSC suggests crystalline beta-alanine trimer tetramer and pentamer domains phase separated from the rubbery PIB. The melting temperature of the crystalline domains increases with the length of the oligo(beta-alanine) segment. Transmission electron microscopy, wide-angle X-ray diffraction, and small-angle X-ray scattering of star-blocks containing tetra(beta-alanine) indicate stacks of hydrogen-bonded beta-sheets dispersed in a soft continuous PIB phase. The crystalline phases form fibrous lamellae with lengths up to similar to 200 nm, widths up to similar to 20 nm, and thicknesses of similar to 2 nm, which is the length of beta-alanine tetramer. Although the oligo(beta-alanine) contents are very low (from 1.5 to 3.6 wt % in the series), the static and dynamic mechanical properties of the starblocks are very different. The elastic moduli of the TPEs increase 5-fold with increasing beta-alanine content. Evidently, the oligo(beta-alanine) domains provide not only physical cross-links but also act as fillers.
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Key words
soft polyisobutylene,self-assembling
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