Poly(2-cycloalkyl-2-oxazoline)s: high melting temperature polymers solely based on Debye and Keesom van der Waals interactions
POLYMER CHEMISTRY(2016)
Abstract
The synthesis of new 2-cycloalkyl-2-oxazoline monomers, namely 2-cyclobutyl (cBuOx), 2-cyclopentyl (cPentOx) and 2-cyclohexyl-2-oxazoline (cHexOx) is described. Their microwave-assisted cationic ringopening polymerisation allowed the synthesis of well-defined homopolymers. The resulting homopolymers are crystalline and have high chemical resistance to organic solvents. The highest melting point was registered for cPentOx (306 degrees C), followed by cHexOx (251 degrees C) and cBuOx (243 degrees C). The crystal structure of the homopolymers was put into evidence by X-ray diffraction and appeared to be similar to that of the poly(2-isopropyl-2-oxazoline). The absence of any hydrogen bonding or pi-pi interactions, makes these compounds a special class of high performance polymers which possess high T-m solely based on Debye and Keesom van der Waals interactions of the side-chains. The copolymerization of cPentOx with 2-ethyl-2-oxazoline (EtOx) and cBuOx, respectively are also reported indicating the formation of near ideal random copolymers. Furthermore, the copolymers of cPentOx with cBuOx with compositions in the range from 0 to 100% revealed a linear dependence of melting temperature with the weight fraction of comonomer. For cPentOx-EtOx copolymers containing up to 25 wt% EtOx a linear decrease of the melting temperature with composition was registered, most likely due to the disturbance of the cPentOx crystalline domains. Further, increasing the EtOx wt% revealed a complex non-linear dependence of glass transition temperature on composition, whereby the glass transition temperature of some copolymers was lower than for pure PEtOx.
MoreTranslated text
Key words
temperature polymers,melting,poly2-cycloalkyl-2-oxazolines
AI Read Science
Must-Reading Tree
Example
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined