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Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Ines G T M Penders,Zacharias Amara,Raphael Horvath,Kai Rossen,Martyn Poliakoff,Michael W George

RSC ADVANCES（2015）

Cited 32|Views4
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Abstract
The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.
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photocatalytic hydroxylation,arylboronic acids
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