铑-ImiFerroPhos配合物对β-取代-α,β-不饱和磷酸酯的不对称氢化
Chinese Journal of Catalysis（2014）
Abstract
将手性二茂铁双膦配体ImiFerroPhos应用到β-取代-α,β-不饱和磷酸酯的不对称氢化反应中,在温和的反应条件下,以高收率及较高对映选择性合成了一系列β-取代的手性磷酸酯,最高获得了92％的ee值.
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Key words
β-Substituted α,β-unsaturated phosphonate,Asymmetric catalytic hydrogenation,ImiFerroPhos ligands,Rhodium (II) complex,Chiral β-substituted alkylphosphonate
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