Synthesis, crystal structure and Hirshfeld surface analysis of bis(caffeinium) hexachloridoplatinum(IV) in comparison with some related compounds

Karim A. Zagidullin,Anton P. Novikov, Daria A. Zelenina,Mikhail S. Grigoriev,Konstantin E. German, A. S. Batsanov

Acta crystallographica. Section E, Crystallographic communications（2023）

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摘要

In the crystal, the cations and anions form a layered structure via strong N—H⋯Cl, weak C—H⋯Cl and C—H⋯O hydrogen bonds and π-stacking interactions.

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关键词

crystal structure, platinum, Pt, caffeine, Hirshfeld surface analysis, hexahalide, pi-stacking

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Synthesis, crystal structure and Hirshfeld surface analysis of bis­(caffeinium) hexa­chlorido­platinum(IV) in comparison with some related compounds