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Synthesis and characterization of manganese(III) and high-valent manganese-oxo complexes and their roles in conversion of alkenes to cyclic carbonates

Punnamchandar Ramidi,Charlette M. Felton,Bishnu P. Subedi,Huajun Zhou,Z. Ryan Tian,Yashraj Gartia,Brad S. Pierce,Anindya Ghosh

Journal of CO2 Utilization（2015）

Cited 37|Views14
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Abstract
•Synthesis and characterization of a new manganese complex of amido-amine ligand.•Manganese complex catalyzed an efficient alkene to cyclic carbonate conversion.•Characterization of a high-valent manganese-oxo species.•Role of high-valent manganese-oxo species in catalysis.
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Key words
Manganese(III) catalyst,Alkene,Carbon dioxide,Cyclic carbonate,High-valent manganese-oxo
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