Raman Spectra And The Symmetry Of Spin-Peierls Crystal Alpha '-Nav2o5

RAMAN SCATTERING(2000)

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摘要
Polarized room-temperature Raman spectra of one-dimensional spin-Peierls single crystal alpha'-NaV2O5 are obtained in backscattering geometries which enabled one to observe all types of the Raman-active modes. The Raman spectra of this crystal with various degree of the deficiency of the Na atoms are also represented. The Raman data are consistent with the recent X-ray measurements and confirm the centrosymmetrical structure of this crystal at room temperature.
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关键词
Raman scattering,spin-Peierls crystals,alpha '-NaV2O5,crystal symmetry,selection rules
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