Synthesis and evaluation of a novel hydrophilic 6,6′-bis(1,2,4-triazin-3-yl)-2,2′-bipyridine ligand for separating actinide(III) from lanthanide(III)
SYNLETT(2016)
摘要
We report the synthesis and evaluation of a novel hydrophilic 6,6-bis(1,2,4-triazin-3-yl)-2,2-bipyridine (BTBP) ligand containing carboxylate groups as a selective aqueous complexing agent for the minor actinides over lanthanides. The novel ligand is able to complex and separate Am(III) from Eu(III) in alkaline solutions selectively.
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关键词
BTBP,americium,separation factor,europium,N-heterocycle,used nuclear fuel,ligand
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