One-step preparation of Pt–M@FP-MWNT catalysts (M=Ru, Ni, Co, Sn, and Au) by γ-ray irradiation and their catalytic efficiency for CO and MeOH

Pt–M@FP-MWNT catalysts (M=Ru, Ni, Co, Sn, and Au) were prepared by one-step γ-ray irradiation. Two different types of functional polymers (FP), such as poly(vinylphenyl boronic acid) (PVPBAc) and poly(vinylpyrorridone) (PVP), were used as anchoring agents, when Pt–M nanoparticles were deposited on the multi-walled carbon nanotube (MWNT) using γ-ray irradiation in aqueous solution at room temperature. The obtained Pt–M@FP-MWNT catalysts were then characterized by XRD, TEM, and elemental analysis. The catalytic efficiency of the Pt–M@FP-MWNT catalysts was examined for CO stripping and MeOH oxidation for use in a direct methanol fuel cell (DMFC). The catalytic efficiency of the Pt–M@FP-MWNT catalyst for MeOH oxidation follows this order: Pt–Sn@FP-MWNT>Pt–Co@FP-MWNT>Pt–Ru@FP-MWNT>Pt–Au@FP-MWNT>Pt–Ni@FP-MWNT catalysts. The CO adsorption capacity of the Pt–M@FP-MWNT catalyst for CO stripping is as follows: Pt–Ru@FP-MWNT>Pt–Sn@FP-MWNT>Pt–Au@FP-MWNT>Pt–Co@FP-MWNT>Pt–Ni@FP-MWNT catalyst.