Dissociative electron attachment to bromotrifluoromethane

International Journal of Mass Spectrometry(2015)

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摘要
•First comprehensive DEA study of CF3Br covering the energy range from 0 to 10eV.•Energy dependency of F−, FBr− and CF2Br− reported in this energy range (0–10eV).•3–5eV contributions assigned as two overlapping a1 and e symmetry shape resonances.•Br− at 0eV consistent with dissociation from the a1 σ*(CBr) anionic ground state.•Br− and F− close to 8eV in agreement with earlier vibrational scattering experiments.
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关键词
Bromotrifluoromethane,CF3Br,Dissociative electron attachment,DEA
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