The reaction of the hydrogen-bridged radical cation [NH 2 C O H O CH 2 ] •+ with dioxygen

Karl J Jobst,Johan K Terlouw,Julien De Winter,Pascal Gerbaux

International Journal of Mass Spectrometry（2013）

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摘要

The title ion (HBRC-1) has recently been shown to be a stable hydrogen-bridged radical cation that is easily accessible by the decarbonylation of ionized methyl oxamate, NH2COCOOCH3.

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关键词

Hydrogen-bridged radical cation,Proton-transport catalysis,Terbody reaction,Tandem mass spectrometry,CBS-QB3 model chemistry

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