Anionarylation of acrylic and methacrylic acids derivatives with p - and m -phenylenebisdiazonium tetrafluoroborates
RUSSIAN JOURNAL OF GENERAL CHEMISTRY(2014)
Abstract
Chloro-, bromo- and thiocyanatoarylation of amides and nitriles of acrylic and methacrylic acids with bisdiazonium salts based on m - and p -phenylenediamines have been studied. 3,3′-[1,4(3)-phenylene]bis[2-halopropanamides(nitriles)] and 2-thiocyanato-(2-methyl)-3-[4(3)-thiocyanatophenyl]propinamides have been obtained as bishaloarylation and monothiocyanatoarylation products, respectively.
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Key words
anionarylation,phenylenebisdiazonium tetrafluoroborate,amide,nitrile of unsaturated acid
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