Cu 2 O nanowires as anode materials for Li-ion rechargeable batteries

SCIENCE CHINA-TECHNOLOGICAL SCIENCES(2014)

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摘要
Li-ion batteries are a key technology for multiple clean energy applications. In this study, Cu 2 O nanowires were obtained by the reduction of cupric acetate with pyrrole. The resulting Cu 2 O nanowires exhibited excellent reversible capacities of 470 mAh g −1 at rate of 1 C after 100 cycles. The results show that the Cu 2 O nanowires had more capacity than materials previously reported. No fading was observed over 100 cycles of charging and discharging. The compound metal Cu and incorporation of the conducting polymer polypyrrole (PPy) improved the conductivity of Cu 2 O and enhanced the stability of the electrode during cycling. The results from this study imply that Cu 2 O nanowires with high capacity and good cycle retention could be excellent candidates as anode materials for Li-ion rechargeable batteries.
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关键词
polypyrrole, cuprous oxide, anode, lithium-ion battery
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