Perkin communications. Radical cyclization in stereospecific introduction of chirality at ‘off template site’ of 1,2-O-isopropylidene-α-D -xylo-hexofuranose
Journal of The Chemical Society-perkin Transactions 1（1990）
Abstract
Bromoacetals derived from 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-ynofuranose (9) undergo facile free radical cyclization leading to the formation of olefinic acetals which are chemially manipulated to introduce either of the chiralities at C-5 of α-D-hexofuranose.
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Key words
chirality,radical cyclization,stereospecific introduction,perkin communications,o-isopropylidene,d-xylo-hexofuranose
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