A ΛΛΛΛ-M4L6 tetrahedral manganese cage: Stereoselective synthesis and captured anion exchange

Kiu-Chor Sham,Guoli Zheng,Yi Pan,Kai-Chung Lau,Shek-Man Yiu,Hoi-Lun Kwong

Inorganic Chemistry Communications（2012）

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摘要

A ΛΛΛΛ-M4L6 tetrahedral manganese cage with a captured perchlorate or trifluoromethanesulfonate anion was synthesized using a chiral quaterpyridine; the captured anion is exchangeable and the removal of the captured ClO4− from the cage was studied by theoretical calculation.

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关键词

Tetrahedral cage,Manganese,Anion exchange,Chiral quaterpyridine

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